Open Access Open Access  Restricted Access Subscription Access

Metal-organic Framework of a Copper(II) Polymer bridged with Succinate Showing Embedded Layers

Saikat Kumar Seth, Kalyanmoy Jana

Abstract


A Cu(II) coordination complex with Succinic Acid [(C4H6O5Cu)n,H2O](1), was conventionally synthesized and structurally characterized by single-crystal X-ray diffraction. X-ray crystallography reveals that the metal-organic framework exhibits di-nuclear paddle-wheel type cage through which a double-stranded chain structure is generated. The intermolecular interactions have been analyzed in a novel visual manner through Hirshfeld surface analysis of the crystal structure employing 3D molecular surface contours where 2D fingerprint plots have been used to examine molecular shapes.

Full Text:

PDF

References


Yang E. C., Zhao H. K., Ding B., et al. Four Novel Three-Dimensional Triazole-Based Zinc(II) Metal−Organic Frameworks Controlled by the Spacers of Di-carboxylate Ligands: Hydrothermal Synthesis, Crystal Structure, and Luminescence Properties. Cryst. Growth Des. 2007; 7(10): 2009–15p.

doi: 10.1021/cg070356n.

Adarsh N. N., Kumar D. K., Dastidar P. Microporous Nanotubular Self-Assembly of a Molecular Chair. Cryst. Growth Des. 2009; 9(7): 2979–83p.

doi: 10.1021/cg8013859.

Cheung K. C., Wong W. L., Ma D. L., et al. Transition metal complexes as electrocatalysts–Development and applications in electro-oxidation reactions. Coord. Chem. Rev. 2007; 251(17-20): 2367–85p.

doi:10.1016/j.ccr.2007.04.004.

Biradha K., Sarkar M., Rajput L. Crystal engineering of coordination polymers using 4, 4′-bipyridine as a bond between transition metal atoms. Chem. Commun. 2006; 4169–79p.

doi: 10.1039/B606184B.

Zaworotko M. J. Molecules to Crystals, Crystals to Molecules.and Back Again? Cryst. Growth Des. 2007; 7(1): 4–9p.

doi: 10.1021/cg0680172.

He H. Y., Collins D., Dai F. N., et al. Construction of Metal−Organic Frameworks with 1D Chain, 2D Grid, and 3D Porous Framework Based on a Flexible Imidazole Ligand and Rigid Benzene di-carboxylates. Cryst. Growth Des. 2010; 10(2): 895–902p.

doi: 10.1021/cg901227h.

Seth S. K., Saha I., Estarellas C., et al. Supramolecular Self-Assembly of M-IDA Complexes Involving Lone-Pair∙∙∙π Interactions: Crystal Structures, Hirshfeld Surface Analysis, and DFT Calculations [H2IDA = iminodiacetic acid, M = Cu (II), Ni (II)]. Cryst. Growth Des. 2011; 11(7): 3250–65p.

doi: 10.1021/cg200506q.

Manna P., Seth S. K., Das A., et al. Anion Induced Formation of Supramolecular Associations Involving Lone pair−π and Anion−π Interactions in Co(II) Malonate Complexes: Experimental Observations, Hirshfeld Surface Analyses and DFT Studies. Inorg. Chem. 2012; 51(6): 3557−71p.

doi: 10.1021/ic202317f.

Mitra M., Seth S. K., Choudhury S. R., et al. MII–Malonate Complexes (M = Mg, Cu, Ni and Co) Characterized by Layered Structures: Experimental Observation, Hirshfeld Surface Analysis and Theoretical Study. Eur. J. Inorg. Chem. 2013, 4679–85p.

doi:10.1002/ejic.201300459.

Mitra M., Manna P., Bauza A., et al. 3-Picoline Mediated Self-Assembly of M(II)–Malonate Complexes (M = Ni/Co/Mn/Mg/Zn/Cu) Assisted by Various Weak Forces Involving Lone Pair−π, π–π, and Anion•••π–Hole Interactions. J. Phys. Chem. B 2014; 118(50): 14713–26p.

doi: 10.1021/jp510075m.

Bruker, SAINT (Version 6.36a) Bruker-AXS Inc.: Madison, Wisconsin, USA, 2002.

Bruker, SMART (Version 5.625) and SADABS (Version 2.03a) Bruker AXS Inc.:Madison, Wisconsin, USA, 2001.

Sheldrick G. M. A short history of SHELX. Acta Crystallogr., Sect. A 2008; 64(1): 112–22p.

doi: 10.1107/S0108767307043930.

Spek A. L. Single-crystal structure validation with the program PLATON. J. Appl. Crystallogr. 2003; 36(1): 7–13p.

doi: 10.1107/S0021889802022112.

Farrugia L. J. WinGX suite for small-molecule single-crystal crystallography. J. Appl. Crystallogr. 1999; 32(4): 837–38p.

doi: 10.1107/S0021889899006020.

Spackman M. A., McKinnon J. J. Fingerprinting intermolecular interactions in molecular crystals. CrystEngComm. 2002; 4(66): 378–92p.

doi: 10.1039/B203191B.

Spackman M. A., Jayatilaka D. Hirshfeld surface analysis. CrystEngComm 2009; 11(1): 19–32p.

doi: 10.1039/B818330A.

Seth S. K., Sarkar D., Jana A. D., et al. On the Possibility of Tuning Molecular Edges To Direct Supramolecular Self-Assembly in Coumarin Derivatives through Cooperative Weak Forces: Crystallographic and Hirshfeld Surface Analyses. Cryst. Growth Des. 2011; 11(11): 4837–49p.

doi: 10.1021/cg2006343.

Seth S. K., Sarkar D., Roy A., et al. Insight into supramolecular self-assembly directed by weak interactions in acetophenone derivatives: crystal structures and Hirshfeld surface analyses. Cryst. Eng. Comm. 2011; 13(22): 6728–41p.

doi: 10.1039/C1CE05670K.

Seth S. K. Discrete cubic water cluster: An unusual building block of 3D supramolecular network. Inorg. Chem. Comm. 2014; 43: 60–3p. doi:10.1016/j.inoche.2014.02.014.

McKinnon J. J., Mitchell A. S., Spackman M. A. Hirshfeld Surfaces: A New Tool for Visualising and Exploring Molecular Crystals. Chem.-Eur. J. 1998; 4(11): 2136–41p. doi: 10.1002/(SICI)1521-3765(19981102)4:11<2136::AID-CHEM2136>3.0.CO;2-G.

McKinnon J. J., Spackman M. A., Mitchell A. S. Novel tools for visualizing and exploring intermolecular interactions in molecular crystals. Acta Crystallogr., Sect. B 2004; 60: 627–68p.

doi:10.1107/S0108768104020300.

Rohl A. L., Moret M., Kaminsky W., et al. Hirshfeld Surfaces Identify Inadequacies in Computations of Intermolecular Interactions in Crystals: Pentamorphic 1,8-Dihydroxyanthraquinone. Cryst. Growth Des. 2008; 8(12), 4517–25p.

doi: 10.1021/cg8005212.

Parkin A., Barr G., Dong W., et al. Comparing entire crystal structures: structural genetic fingerprinting. CrystEngComm 2007; 9(8), 648–52p.

doi 10.1039/B704177B.

Seth S. K. Tuning the formation of MOFs by pH influence: X-ray structural variations and Hirshfeld surface analyses of 2-amino-5-nitropyridine with cadmium chloride. Cryst. Eng. Comm. 2013; 15(9): 1772–81p.

doi: 10.1039/C2CE26682B.

Wolff S. K., Grimwood D. J., McKinnon J. J., et al. Crystal Explorer 2.1; University of Western Australia: Perth, Australia, 2007.

Zhang C.-Z., Mao H.-Y., Wang Y.L., et al. Syntheses of two new hybrid metal-organic polymers using flexible aliphatic di-carboxylates and pyrazine: Crystal structures and magnetic studies. J. Phys. Chem. Solids 2007; 68(2): 236–42p. doi:10.1016/j.jpcs.2006.11.001.




DOI: https://doi.org/10.37628/ijssm.v1i1.3

Refbacks

  • There are currently no refbacks.